MATERIAL SAFETY DATA SHEET
ALKALINITY CONTROL
1. IDENTIFICATION OF THE PREPARATION AND OF THE COMPANY
PRODUCT NAME: Alkalinity control
APPLICATION: INDUSTRIAL WATER TREATMENT
COMPANY IDENTIFICATON: delaranrooz.co
Address: .Unit16,No217,Kalhor Ave,Navvab Ave,Tehran-Iran
EMERGENCY TELEPHON NUMBER: +9821 66948831-66947491-66947522
2. COMPOSITION/ INFORMATION ON INGREDIENTS
CHEMICAL DESCRIPTION :
Water, polyment sodium hydroxide
HAZARDOUS INGREDIENTS:
CAS NO. EINECS NO. CHEMICAL NAME WT % SYMBOL R-PHRASES
1310-73-2 2151855 sodium hydroxide 20-30 C 35
3. HAZARDS IDENTIFICATION
HUMAN HEALTH HAZARDS -ACUTE:
INHALATION:
Corrosive to respiratory system.
SKIN CONTACT:
Causes severe burns.
EYE CONTACT:
Causes sever burns. May cause permanent damage to eyes.
INGESTION:
Corrosive causes burns to gastro -intestinal tract. Nausea, vomiting and Stomach pain may occur. In severe causes blood may be vomited.
HUMAN HEALTH HAZARDS-CHRONIC:
None known
ENVIRONMENTAL HAZARDS
None known.
PHYSICAL AND CHEMICAL HAZARDS :
Gives off hydrogen by reaction with metal.
4. FIRST-AID MEASURE
INHALATION:
Remove to fresh air, rest; treat symptomatically .obtain medical attention immediately.
SKIN CONTACT:
Speed is essential. Remove contaminated clothing .wash off affected area immediately with plenty of water. if severe burns have occurred and areas of skin are destroyed ,cover the burned area with clean dry non fluffy material an obtain medical attention.
EYE CONTACT :
Speed is essential. Immediately gently irrigate with clean water for at least 15 minutes. Move eyeball and keep eyelids wide open and apart whilst irrigating. Obtain medical attention imp immediately.
INGESTION :
DO not induce vomiting without medical advice. if conscious washout mouth and give one pint of water to drink .Obtain medical attention immediately.
ADDITIONAL INFORMATION
Note to physician: probable mucosal damage may contraindicate the use of gastric lavage.Measures against circulatory shock, respiratory depression and convulsions may be needed.
5. FIRE-FIGHTING MEASURES
EXTINGUISHING MEDIA :
Not expected to burn. Use extinguishing media appropriate for surrounding fire.
UNSUITABLE EXTINGUISHING MEDIA:
Not applicable.
FIRE AND EXPLOSION HAZARD:
Not applicable
SPECIAL PROTECTIVE EQUIPMENT FOR FIRE FIGHTING:
In case of fire, wear a full face positive- pressure self contained breathing apparatus and protective suit.
6. ACCIDENTAL RELEASE MEASURES
PERSONAL PRECAUTIONS :
Keep people away from and upwind of spill / leak. Ensure adequate ventilation. An approved
respirator must be worn if the occupational exposure limit is likely to be exceeded. Wear chemical resistant apron chemical splash goggles, impervious gloves and Wellington boots.
A full slicker suit is recommended if gross exposure is possible.
ENVIRONMENTAL PRECAUTIONS :
Do not allow to enter sewers or water courses. if spillage does enter sewers or water courses, immediately inform the appropriate water authorities
METHODS FOR CLEANING UP:
Contain and absorb with sand or vermiculite and mix well. Collect up and remove to a safe place until disposal. Wash site of spillage thoroughly with water and detergent. Assistance can obtained from waste disposal companies.
7. HANDLING AND STORAGE
HANDLING:
Prevent contact with skin, eyes and clothing. If clothing is contaminated remove clothing and thoroughly wash the affected area. Launder contaminated clothing before reuse. Do not take internally. Use with adequate ventilation
STORAGE CONDITIONS:
Keep container tightly closed in a cool well-ventilated place. Store separately from acids storage for more than one year is not recommended. Avoid use of aluminum, zinc, tin and their alloys and polyester elastomers.
CONSTRUCTION MATERIAL COMPATIBILITY. COMPATIBLE WITH:
Equipment for storage and application should be constructed from stainless steel , cast iron PVC polypropylene, polyethylene, acrylic resin, nylon, butyl, rubber, nitrile rubber, natural rubber or ethylene
propylene rubber.
8. EXPOSIN CONTROL/PERSONAL PROTECTION
OCCUPATIONAL EXPOSURE LIMITS
NATIONAL REGULATIONS GERMANY
Sodium hydroxide: MAK 2mg/m3
NATIONAL REGULATIONS UK
Sodium hydroxide : OES 2mg/m3
Ammonia ;OES 25 PPM (TWA), OES 35PPM (STEL)
NATIONAL REGULATIONS SWITZERLAND
Sodium hydroxide :TWA2mg/m3,STEL4 mg/m3
NATIONAL REGULATIONS FRANCE
Sodium hydroxide : VME2 mg/m3
NATIONAL REGULATIONS HOLLAND
Sodium hydroxide :MAC2mg/m3C
NATIONAL REGULATIONS SWEDEN
Sodium hydroxide: TGV2 mg/m3
Ammonia : NGV 25 ppm/18 mg/m3, TGV50 ppm/35 mg/m3
NATIONAL REGULATIONS FINLAND
Sodium hydroxide :TWA 2 mg/m3
NATIONAL REGULATIONS NORWAY
Sodium hydroxide :TLV2 mg/m3
Ammonia : TL V 25 ppm / 18 mg/m3
NATIONAL REGULATIONS DENMARK
Sodium hydroxide: TWA2mg/m3
Ammonia :GV 25 ppm /18 mg/m3
ENGINEERING MEASURES
USE closed dosing system Local exhaust ventilation if necessary to control airborne levels below the exposure guidelines.
RESPIRATORY PROTECTION:
An approved respirator must be worn if the occupational exposure limit is likely to be exceeded Ammonia rich air will be displaced when refilling stock tanks. if it is necessary to remain near to
the container at such times and the area is poorly ventilated an approved respirator should be worn . Filter -type k, Green.
HAND PROTECTION:
Rubber gloves, PVC gloves, Nitrile gloves HYGIENE RECOMMENDATIONS:
SKIN PROTECTION :
Apron and boots.
EYE PROTECTION ;
Chemical splash goggles
HYGIENE RECOMMENDATIONS :
Keep an eye wash fountain available. Keep a safety shower available.
9. PHYSICAL AND CHEMICAL PROPERTIES
NOTE: These physical properties are typical values for this product
FORM : Liquid
COLOUR: Dark brown
ODOUR : Slight fishy.
VALUE UNIT TEST METHO
BOILING POINT : NE
MELTING POINT: NA
FLASH POINT : NA
AUTOFLAMMABILITY: NA
EXPLOSION LIMITS : NA
VAPOR PRESSURE NE
RELATIVE DENSITY: (1.25-1.29) ASTM D-1298
SOLUBILITY IN WATER : Complete
PH >12
OCTANOL/ WATER COEFFICIENT : NE
VISCOSITY NE
BULK DENSITY : NA
FREEZING POINT : <-2.2 OC ASTM D-1177
POUR POINT : NE
Abbreviation : NE= not evaluated, NA= not applicable, NR =not relevant
10. STABILITY AND REACTIVITY
STABILITY:
Stable under ambient conditions .
CONDITION TO AVOID:
None known.
MATERIALS TO AVOID
Acids. Chlorinated hydrocarbons. Gives off hydrogen by reaction with metals.
HAZARDOUS DECOMPOSITION PRODUCTS :
None
11. TOXICOLOGICAL INFORMATION
ACUTE TOXICITY DATA:
The following results are for the active ingredients
ACUTE LETHALITY VALUES:
No data available.
SENSITIZATION:
No data available.
CHRONIC TOXICITY DATA:
No data available.
12. ECOLOGICAL INFORMATION
PERSISTENCY AND DEGRADATION:
No data available.
MOBILITY AND BIOACCUMULATION POTENTIAL:
No data available.
ECOTOXICOLOGICAL EFFECTS:
No data available.
13. DISPOSALCONSIDERATION
Via authorized contractor.
NATIONAL REGULATIONS UK
In accordance with the Environmental protection (Duty of care) Regulations 1996 apply.
NATIONAL REGULATIONS SWEDEN
Waste treatment group :5.8
NATIONAL REGULATIONS NORWAY
The waste is to be treated as problem waste and has to be submitted to the problem waste plant. Waste treatment group :13
NATIONAL REGULATIONS DENMARK
Waste treatment group :H
14. TRANSPORT INFORMATION
Class : 8 packing Group :ll
UN NO:3266
Proper shipping name: CORROSIVE LIQUID BASICINORGANIC:
N.O.S. Contains :Sodium hydroxide
ADR/RID ,H,I, n.: 80
ADR/RID,NO 47ْ (b)
IMDG page 8147-1
Ems -Nr: 8-15
MFAG-Nr 760
15. REGULATORY INFORMATION
EC CLASSIFICATION:
HAZARD SYMBOL: CRROSIVE
Contains: sodium hydroxide (20-30%)
RISK PHRASES:
R35 causes severe burn
SAFETY PHRASES:
S26 in case of contact with eyes. Rinse immediately with plenty of water and seek medical advice.
S28 After contact with skin, wash immediately with plenty of water .s36/37/39 wear suitable protective clothing, gloves and eye/face protection.s45 in case of accident or if you feel unwell seek medical advice immediately (show the label where possible).
NATIONAL REGULATIONS UK
COSHH regulations apply.
A precaution card is available and should be displayed wherever this product is used and stored (Ref. CR).
