PRODUCT NAME:                                              WATER TERATMENT

APPLICATION:                                                       

COMPANY IDENTIFICATON:                          Delaran Rooz co.

                                                                                                  

EMERGENCY TELEPHON NUMBER:            +9821 66948831& 66947522

 CHEMICAL    DESCRIPTION :

 Water Borate, sodium nitrite, sodium hydroxide, Nitrate, silicate, polymer

 HAZARDOUS  INGREDIENTS :

CAS NO.    EINECS NO.      CHEMICAL NAME           WT%      SYMBOL    R-PHRASES

7632-00-0     2315559             Sodium nitrite                      5-15%       O,T               8-25

1310-73-2     2151855             Sodium  hydroxide               0-2            C                  35

1344-09-8     2156874             Sodium silicate                     20-30         C                 38.41

 

  

HUMAN HEALTH HAZARDS - ACUTE:

INHALATION:

May  cause  tightness in the  chest with  shortness of breath or coughing  and a sore  throat.

SKIN   CONTACT :

Irritating  to skin.

EYE   CONTACT :

Risk of  serious  damage to eyes. Can cause  sever  irritation.

 INGESTION:

There may be irritation to the gastro-intestinal  tract with  nausea and vomiting. Toxic if swallowed Components of the product   create formation  of  methaemoglobin .   Pregnant   women   are   particularly sensitive  to methemoglobinemia.

HUMAN  HEALTH HAZARDS-  CHRONIC:

Repeated  ingestion of small  amounts of sodium  nitrite causes  drops in blood pressure rapid pulse  headaches and  visual  disturbances. It may also  react  with organic  amines  in the body to form carcinogenic

ENVIRONMENTAL  HAZARDS

Nitrite  is   toxic       fish.

PHYSICAL  AND  CHEMICAL  HAZARDS :

If  product  is allowed to dry the sodium nitrite  is an oxidizing  agent  and can  initiate  the combustion  of other  materials.

Contact  with acids  liberates toxic  gas

Gives  off  hydrogen  by  reaction  with  metals.

INHALATION:

Usually  not  necessary  unless aerosol/  mists  are generated . Remove to   fresh  air,  rest.   Treat   symptomatically.  Obtain   medical    attention immediately.

SKIN CONTACT :

Remove  contaminated  clothing . Wash  off  affected  area  immediately with  plenty  of  water. If  skin irritation  persists .obtain  medical attention

EYE CONTACT :

Speed is  essential. immediately  gently  irrigate  with  clean  water for at least15 minutes Move eyeball  and  keep  eyelids  wide open  and  apart whilst  irrigating. Obtain  medical  attention   immediately.

INGESTION :

Do not  induce  vomiting  without  medical  advice. if  conscious  washout mouth  and give one  pint of  water  to  drink . Obtain   medical   attention immediately.

EXTINGUISHING  MEDIA :

Not expected to burn. Use extinguishing  media  appropriate  for  surrounding fire.

UNSUITABLE  EXTINGUISHING MEDIA:

Not  applicable.

FIRE  AND  EXPLOSION  HAZARD:

May  evolve  toxic  gases or  fumes  under   fire   conditions.  Oxides   of nitrogen. Oxides  of carbon. if product  is  allowed  to  dry. the  sodium  nitrite  is an  oxidizing   agent and  can  initiate  the  combustion  of  other  materials.

SPECIAL  PROTECTIVE  EQUIPMENT  FOR FIRE  FIGHTING:

In case of fire, wear a full face positive- pressure self contained breathing apparatus and protective suit.

PERSONAL  PRECAUTIONS :

Wear  chemical  resistant  apron. chemical  splash  goggles, impervious gloves and  Wellington  boots A full  slicker suit  is recommended if gross exposure  is  possible

ENVIRONMENTAL  PRECAUTIONS :

Do not allow to enter sewers or water courses. if spillage does enter sewers or water  courses, immediately  inform  the  appropriate water  authorities                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                              

                                                                                                                                                                     

METHODS  FOR  CLEANING  UP:

Contain and absorb with sand or vermiculite and mix well. Collect up and remove to a safe place   until disposal. Wash site of spillage thoroughly with water and detergent. Assistance can obtained   from waste disposal companies. Do  not   use   cotton  waste, sawdust  or  other  combustible  substances  as  absorbent  materials. These  may  ignite when dried out.

HANDLING:

Avoid contact  with  skin and  eyes . If clothing  is  contaminated . Remove clothing  and thoroughly wash the  affected  area. Launder  contaminated clothing  before  reuse. Avoid  generating  aerosols  and  mists Avoid use of  brass, aluminum, zinc  and  their  alloys and  galvanized metals. Gives

Off hydrogen  by  reaction   with metals.

STORAGE  CONDITIONS :

Keep container tightly closed. Store separately from acids, organic materials and reducing  agents. Storage   for  more   than  two  years   is not recommended

OCCUPATIONAL   EXPOSURE  LIMITS

NATIONAL  REGULATIONS  GERMANY

Sodium  hydroxide:MAK 2mg/m3

NATIONAL  REGULATIONS  UK

Sodium  hydroxide : OES 2mg/m3

NATIONAL  REGULATIONS  SWITZERLAND

Sodium  hydroxide :TWA2mg/m3,STEL4 mg/m3

NATIONAL  REGULATIONS  FRANCE

Sodium  hydroxide : VME2 mg/m3

NATIONAL  REGULATIONS  HOLLAND

Sodium  hydroxide :  MAC2  mg/m3C

NATIONAL  REGULATIONS   SWEDEN

Sodium  hydroxide: TGV2  mg/m3

NATIONAL    REGULATIONS   FINLAND

Sodium  hydroxide  :TWA 2 mg/m3

NATIONAL   REGULATIONS   NORWAY

Sodium  hydroxide :TLV2 mg/m3

NATIONAL  REGULATIONS  DENMARK

Sodium  hydroxide: TWA2mg/m3

NATIONAL  REGULATIONS  AUSTRIA

Sodium  hydroxide : MAK 2 mg/m3

ENGINEERING    MEASURES

USE   closed dosing system Local exhaust ventilation if  necessary to control  airborne  levels below the exposure  guidelines.

RESPIRATORY  PROTECTION:

Respiratory  protection  not   normally  needed  .  An  approved  respirator must  be  worn if the occupational  exposure  limit is likely to be exceeded( this is unlikely to occur  unless significant  aerosols/ mists  are generated

HAND  PROTECTION:

Chemical   splash  goggles.

HYGIENE      RECOMMENDATIONS:

Keep an eye wash fountain available.

                                 

FORM :                                                     Liquid

COLOUR:                                                 Dark blue

ODOUR :                                                  None

                                                                  VALUE        UNIT       TEST METHO

BOILING POINT :                                   NE

MELTING POINT:                                  NE

FLASH  POINT  :                                     NA

AUTOFLAMMABILITY:                        NA

EXPLOSION  LIMITS :                           NA

VAPOUR PRESSURE                              same as water

RELATIVE  DENSITY:                          (1.360-1.370)                20ْC                                                               

SOLUBILITY  IN WATER :                    Complete

PH                                                              >12.2

OCTANOL/ WATER COEFFICIENT :   NE

VISCOSITY                                              NE

BULK  DENSITY :                                   NE

FREEZING POINT :                                 NE

POUR  POINT :                                         NE

Abbreviation : NE= not evaluated, NA= not applicable, NR =not  relevant

 

STABILITY:

Stable under  ambient  conditions .

CONDITION TO AVOID:

Freezing temperature.

MATERIALS TO AVOID

Acids. Organic materials  and  reducing  agents. Cyanides  and ammonium compounds . Gives  off  hydrogen  by  reaction  with  metals.

HAZARDOUS   DECOMPOSITION  PRODUCTS :

May evolve  toxic  gases  or  fumes  under   fire   conditions, oxides of nitrogen. Oxides  of  carbon

                                                                                                                                                                                                                 

ACUTE TOXICITY DATA:                   The following results are for the active ingredients

ACUTE LETHALITY VALUES:

Sodium  nitrite  oral  (rat ) : LD 50 = 85 mg/kg

PRIMARY (DRAIZE TEST) SKIN/EYE

No data available.

SENSITIZATION:

No data available.

CHRONIC TOXICITY DATA:

No data available.

PERSISTENCY AND DEGRADATION:

No data available.

MOBILITY   AND    BIOACCUMULATION    POTENTIAL:

No data available.

ECOTOXICOLOGICAL EFFECTS:

No data available.

Via authorized   contractor.

NATIONAL  REGULATIONS  GERMANY

Waste  code : 52725

Contaminated  receptacles :  contaminated  wrapping . Receptacles. Containers  must  be  completely  drained  cleaned  prior  to recycling or recondition..

Clean  contaminated  surfaces  with water  or aqueous  cleaning  agents.

NATIONAL  REGULATIONS  UK

In accordance  with  the environmental  protection (Duty of care ) Regulations  1991 . Special  waste Regulations  1996  apply.

Class :                                      8                                                        packing  Group :ll

                                                                                                             UN NO:3266

Proper shipping name:    CORROSIVE  LIQUID BASICINORGANIC:               

                                             N.O.S. Contains :Sodium  hydroxide

ADR/RID ,H,I, n.:                80

ADR/RID,NO                       47ْ (b)

IMDG   page                         8147-1

Ems -Nr:                              8-15

MFAG-Nr                             760

EC CLASSIFICATION:

HAZARD  SYMBOL:            TOXIC, IRRITANT

 

T, TOXIC

Contains :        sodium nitrite, sodium hydroxide, sodium silicate

RISK   PHRASES :

R25  Toxic if swallowed R38  Irritating  to skin.R41 RISK of serious damage      to  eyes.

SAFETY   PHRASES :

S26  in case of contact with eyes , rinse immediately with plenty of water and seek medical advice. S37/39 wears  suitable gloves and eye/face  protection. S45 in case of accident or if you feel unwell seek medical  advice  immediately (show  the  label  where  possible ). Do not clean  up spills with  sawdust. Cotton  waste or  other combustible absorbent  materials.

NATIONAL   REGULATIONS      GERMANY

VbF-  klasse: None

WHG- WG: 2

TA-Luft: -

Berufsgenossensch. vorschriften : Take  notice of UVV- chemie. Hinweise zur    beschaftigungsbeschrankung : observes 15 ofregulations  for hazardous  substances.

NATIONAL  REGULATIONS  UK

COSHH  regulations  apply. A precaution  card is available  and should be  displayed  wherever  this product is used and stored.